国際交流・公開研究セミナー開催のお知らせ

日程: 2013年10月18日（金） 16：20 - 18：00
場所: 後楽園キャンパス 6号館4階　6429号室

日程: 2013年10月18日（金） 16：20 - 18：00

場所: 後楽園キャンパス 6号館4階　6429号室

講演者: Prof. Martin Albrecht
（School of Chemistry and Chemical Biology, University College Dublin，Ireland）

内容: 題目：
New ligands for catalytic applications: impact and activity of mesoionic carbenes

　アイルランド、ダブリン大学化学･生命化学科、 Martin Albrecht教授が来日される機会に、最近その応用が注目されているメソイオンカルベン金属錯体の配位子の性質と触媒作用に関してご講演をお願いしました。是非ご参集ください。

アブストラクト：
N-heterocyclic carbenes (NHCs) have had a substantial impact on organometallic chemistry and on catalysis in particular, which has been largely associated with the unique bonding features of these ligands. The covalent metal-ligand bond combined with the much stronger donor ability of carbenes as compared to phosphines has provided access to a variety of new reaction pathways and increased activities in catalytic reactions.
We have been interested in furthering the specific (donor) properties of the NHC ligand in order to mediate the activation of strong and typically less reactive bonds. To this end, we have been actively pursuing the development and application of mesoionic N-heterocyclic carbenes, i.e. homologues of classical NHCs that do not feature a neutral resonance structure. These mesoionic carbenes display exceptionally strong donor ability when compared to other formally neutral ligands such as phosphines and classical Arduengo-type carbenes. We have recently obtained evidence that the mesoionic character also entails ligand-centered reactivity, which has been exploited in bond activation catalysis. This presentation will discuss some fundamental aspects and unique reactivity patterns of these carbenes, and will highlight most recent developments in (oxidation) catalysis (for an example, see below).

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参加費: 無料

参加手続き: 事前申し込み不要

連絡先：中央大学理工学部応用化学科
石井　洋一